How to use this tool
- Enter acid dissociation constant ka, initial acid concentration.
- Select Calculate to view the result.
- Check the method and assumptions below before using the result.
The method, explained
Solve x² + Ka·x − Ka·C = 0 with x = 2KaC/(sqrt(Ka² + 4KaC) + Ka), then pH = −log10(x). The stable form avoids subtractive cancellation.
Using acid dissociation constant ka = 0.000018, initial acid concentration = 0.1 mol/L, the result is 2.87527706 pH. Change these example inputs to match your task; use the method above to check each step.
Understanding your result
No. It solves the quadratic rather than assuming dissociation is negligible relative to the initial concentration. Water and activity effects remain outside the model.
What to keep in mind
Neglects water autoionization and activity effects. Rejects predicted [H+] below 10⁻⁶ mol/L. Not for mixtures or polyprotic acids. Educational calculation only; use validated procedures for laboratory work.
Reference: OpenStax Chemistry 2e — chemical quantities and models
Common questions
Does this use the square-root approximation?
No. It solves the quadratic rather than assuming dissociation is negligible relative to the initial concentration. Water and activity effects remain outside the model.
Are my inputs uploaded?
No. This calculation runs in your browser without an account or an external API.
Methodology maintained by ClarityKit. How these tools are built and checked.